Goal: Discovering new inorganic compounds drives our research, focusing on unique electronic properties for improved performance in electronics, optoelectronics, and renewable energy. Through meticulous experimentation, we aim to uncover compounds with enhanced efficiency and expanded functionality.
Motivation: Canada’s commitment to carbon neutrality by 2050 can be achieved by understanding the challenges with existing materials used for sustainable energy. Along with this, Canada’s Semiconductors Council’s report for “Road Map 2050” seeks to develop semiconductor chip independence by developing technologies for conventional materials.1 The lack of implementable, scalable, and cost-effective technologies to harvest energy (in the case of solar energy), convert energy (into chemical energy – e.g., sustainable fuels such as hydrogen for transportation), and store energy (e.g., in batteries or carbon-neutral fuels on both household and grid-scales) is arguably the most significant technological bottleneck we currently face. The discovery of new inorganic compounds will be important towards Canada’s technological independence from the global supply chain and the development of new sustainable energy technologies
Objectives
1) Design rational principles for noncentrosymmetric structures with band gaps >2 eV to study their NLO properties.
2) Use mixed anions to synthesize lower dimensional structures for higher crystallinity and surface area for catalysis.
3) organic cation intercalation in 2D materials to offer greater magnetic tunability and discover new room temperature ferromagnets.
Methodology
High-temperature synthesis (>400 °C) using molten flux as reactants
Solution-based synthesis (solvothermal and hydrothermal) will also be pursued as many phases are stable at low temperatures.
Outcomes: By advancing material discovery, we will contribute to semiconductor science, paving the way for next-generation devices with enhanced capabilities and sustainability
Selected Publications
"Discovery of Noncentrosymmetric Sr3As2S7 and Sr3As2Se2.5S4.5 Featuring As3+/As5+ Coordination and Their Strong Nonlinear Optical Response" 2026, Chemistry of Materials
Vidyanshu Mishra, Jinseong Kim, Jong-Hoon Lim, Manya Rishi, Joon Jang*, and Abishek K. Iyer*
Unconventional Mechanism in the Selective Removal of Lead and Cadmium from Acidic Media Using Nax+2ySn4−yS8·3H2O (NMS-7) Journal of American Chemical Society, 2026
Anastasia D. Pournara, Yukun Liu, Thomas S. Ie, Jinlei Cui, Abishek K. Iyer, Alann P. Au, II, Dimitrios A. Evangelou, Vinayak P. Dravid, and Mercouri G. Kanatzidis
Stabilization of the Polar Structure and Giant Second-Order Nonlinear Response of Single Crystal γ-NaAs0.95Sb0.05Se2 Advanced Functional Materials, 2022, 2211969
Abishek Iyer; Jingyang He* (contributed equally); Hongyao Xie; Devin Goodling; Duck-Young Chung; Venkatraman Gopalan; Mercouri G. Kanatzidis.